Download Environmental Applications of Nanoscale and Microscale by Cherie Geiger, Kathleen Carvalho-Knighton PDF

By Cherie Geiger, Kathleen Carvalho-Knighton

content material: 1. A evaluate of Environmental purposes of Nanoscale and Microscale Reactive steel debris; LABORATORY AND MECHANISTIC experiences; 2. Use of Nanoparticles for Degradation of Water Contaminants in Oxidative and Reductive Reactions; three. Small Particle measurement Magnesium in One-pot Grignard-Zerewitinoff-like Reactions lower than Mechanochemical stipulations: at the Kinetics of Reductive Dechlorination of power natural pollution (POPs); four. Proposed Mechanisms for the Dechlorination of PCBs utilizing Microscale Mg/Pd in Methanol; five. PBDE Degradation with Zero-Valent Bimetallic structures; 6. fast Dechlorination of Polychlorinated Dibenzo-p-dioxins by means of Nanosized and Bimetallic Zerovalent Iron: impact of Palladization and Toxicity switch; 7. Degradation of TNT, RDX, and TATP utilizing Microscale routinely Alloyed Bimetals; eight. Arsenic elimination by way of Nano-scale 0 Valent Iron and the way it truly is stricken by common natural subject; nine. Nanostructured Multifunctional fabrics for Environmental Remediation of Chlorinated Hydrocarbons; box SIMULATION reviews; 10. Treatability learn for a TCE infected region utilizing Nanoscale- and Microscale-Zerovalent Iron debris: Reactivity and Reactive lifestyles Time; eleven. Electrokinetically more advantageous elimination and Degradation of Subsurface toxins utilizing Nanosized Pd/Fe Slurry; expertise DEMONSTRATIONS AND box functions; 12. prestige of nZVI know-how classes realized from North American and foreign Implementations; thirteen. Iron Nanoparticles for In Situ Groundwater Remediation of Chlorinated natural Solvents in Taiwan; 14. functional functions of Bimetallic Nanoiron debris for Reductive Dehalogenation of Haloorganics: customers and demanding situations; 15. Use of Nanoscale Iron and Bimetallic debris for Environmental Remediation: A evaluate of Field-scale functions; INDEXES; writer INDEX; topic INDEX

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Concentration of total chlorinated compounds (CT + CF) vs. 5 mL solution of 50 mg/L CT); ■ – electron donor plus catalyst; ● – control electron donor only (no catalysts). After Dror et al. (3). A second example of reductive transformation of chlorinated organic compounds is the reductive dechlorination of atrazine. Atrazine, 2-chloro-4(ethylamine)-6-(isopropylamine)-s-triazine, is a widely used herbicide that is known to be relatively persistent in soil. As such, it has a strong potential to contaminate surface water and groundwater, despite its moderate aqueous solubility (43-45).

Furthermore, a rationale is derived for the observed complete reductive dechlorinations to benzene, formed at approximately 100 % yield (mole/mole, based on DCB or MCB). The rate constants for the formation of intermediates 3-chlorophenylmagnesium chloride and phenylmagnesium chloride were calculated. These correspond well to similar data previously reported elsewhere. The time-dependent development of the actual reactive surface of the small-sized magnesium particles during grinding was assessed.

2006, 66, 288-294. Khedr, M. ; Abdel Halim, K. ; Nasr, M. ; El-Mansy, A. M. Mater. Sci. Eng. 2006, A 430, 40-45. Kapinu, E. ; Viktorova, T. ; Khalyavka, T. A. Theor. Chem. 2006, 42, 282-286. ; Parravicini, G. ; Salghetti-Drioli, F. Phys. Rev. B 52 1995, 1433-1436. Jernaigan, G. ; Somorjai, G. A. J. Catal. 1994, 147, 567-577. Huang, T. ; Tsai, D. ; Catal. Lett. 2003, 87, 173-178. ; Pajonk, G. ; Albers P. Environ. Sci. Technol. 1996, 30, 1261-1267. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2009.

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