By Steven D. Burke, Rick L. Danheiser
Recognising the serious want for bringing a convenient reference paintings that offers with the most well-liked reagents in synthesis to the laboratory of practicing natural chemists, the Editors of the acclaimed Encyclopedia of Reagents for natural Synthesis (EROS) have chosen crucial and invaluable reagents hired in modern natural synthesis.
instruction manual of Reagents for natural Synthesis: Oxidizing and decreasing brokers, offers the unreal chemist with a handy compendium of knowledge focusing on crucial and regularly hired reagents for the oxidation and relief of natural compounds, extracted and up to date from EROS. The inclusion of a bibliography of experiences and monographs, a compilation of natural Syntheses methods with confirmed experimental info and references to oxidizing and lowering brokers will make sure that this instruction manual is either accomplished and handy.
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Extra resources for Handbook of reagents for organic synthesis
Example text
O'Connor, J. JACS 1974,96,3929. 53. ;Widmer, J. JACS 1978,100, 7086. 54. ; Kemp, D. S . S 1988,32. Emmanuil I. Troyansky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia Aluminum Hydridel [7784-2I -61 ~~ lactones, from which the corresponding alcohol is the isolated product. Amides, nitriles, oximes, and isocyanates are reduced to amines. Nitro compounds are inert to AlHs. Sulfides and sulfones are unreactive, but disulfides and sulfoxides can be reduced. Tosylates are also not reduced by AlH3.
Ether linkages of various substrates, for example g l y c o s i d e ~1,3-dioxolanes$ ,~~ tetra hydro fur an^,^^^^ Lists ofAbbreviations and Journal Codes on Endpapers g c 0 ,O0C 3. ^^,^^ For some reactions mediated by aluminum activated with mercury(11) chloride, also see Aluminum. Related Reagents. See Classes R-1, R-2, R-3, R-5, R-6, R9, R-10, R-15, R-16, R-21, R-22, R-23, R-24, R-25, R-27, R-30, R-31, and R-32, pages 1-10, 1 . Smith, M. Reduction Techniques and Applications in Organic Synthesis; Augustine, R.
9. ; Azerad, R. JOM 1989,367,85. 10. ; Zanarotti, A. LA 1989, 1257. ; Fujisawa, T. BCJ 1989, 62, 3851. ; Yamanaka. ; Mobele, B. ; Shimizu, M. TL 1991,32,399. 11. ; Horak, R. ; Meth-Cohn, 0. ; Golding, B. ; Royal Society of Chemistry: London, 1990; p 350. 12. ; Seebach, D. C 1989,43,351. ; Ohno, A. TL 1991,32,7075. 13. ; Ohno, A. TL 1990,31,3631. ; Ohno, A. TL 1990,31,267. ; Oka, S . ; Ohno, A. BCJ 1989, 62, 875. ; Yamashita, T. Enz. Microb. Technol. 1991,13, 834. 14. ; Ragoussis, N. TL 1990, 31, 1615.