Download Inventing Reactions by Barry M. Trost (auth.), Lukas J. Gooßen (eds.) PDF

By Barry M. Trost (auth.), Lukas J. Gooßen (eds.)

Barry Trost: Transition steel catalyzed allylic alkylation.- Jeffrey W. Bode: Reinventing Amide Bond Formation.- Naoto Chatani and Mamoru Tobisu: Catalytic adjustments regarding the Cleavage of C-OMe Bonds.- Gregory L. Beutner and Scott E. Denmark: The interaction of Invention, statement and Discovery within the improvement of Lewis Base Activation of Lewis Acids for Catalytic Enantioselective Synthesis.- David R. Stuart and Keith Fagnou: the invention and improvement of a Palladium(II)-Catalyzed Oxidative Cross-Coupling of 2 Unactivated Arenes.- Lukas Gooßen and Käthe Gooßen: Decarboxylative Cross-Coupling Reactions.- A. Stephen ok. Hashmi: Gold-Catalyzed natural Reactions.- Ben record: constructing Catalytic uneven Acetalizations.- Steven M. Bischof, Brian G. Hashiguchi, Michael M. Konnick, and Roy A. Periana: The De NovoDesign of CH Bond Hydroxylation Catalysts.- Benoit Cardinal-David, Karl A. Scheidt: Carbene Catalysis: past the Benzoin and Stetter Reactions.- Kenso Soai and Tsuneomi Kawasaki: uneven autocatalysis of pyrimidyl alkanol.- Douglas C. Behenna and Brian M. Stoltz: ordinary items as idea for response improvement: Catalytic Enantioselective Decarboxylative Reactions of Prochiral Enolate Equivalents. Hisashi Yamamoto: Acid Catalysis in natural Synthesis.

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2 Nickel-Catalyzed Carbon–Oxygen Bond Transformations . . . . . . . . . . . . . . . . . 1 Cross-Coupling Reactions with Organometallic Reagents . . . . . . . . . . . . . . 2 Other Reactions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Carbon–Oxygen Bond Transformations Catalyzed by Other Metals .

2 Nickel-Catalyzed Carbon–Oxygen Bond Transformations . . . . . . . . . . . . . . . . . 1 Cross-Coupling Reactions with Organometallic Reagents . . . . . . . . . . . . . . 2 Other Reactions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Carbon–Oxygen Bond Transformations Catalyzed by Other Metals . . . . . . . . . . . . 4 Synthetic Applications . . . . . . . . . . . . .

5 Summary and Outlook . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . M. Tobisu (*) and N. jp 36 37 37 41 44 46 51 51 36 M. Tobisu and N. Chatani 1 Introduction Chemical synthesis has been revolutionized by the invention of transition metalcatalyzed aromatic substitution reactions of aryl halides (Eq.

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