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18]. 21]. Convergence to the bulk composition was shown to occur within less than three to five atomic layers. For a solid solution with components of significantly different atomic radii the surface segregation process needs to take into account the strain energy within the lattice resulting from such a geometric Crystallite Morphology ι 1 1 r 1175 Κ Vacuum Pretreatment 675 Κ H_ Pretreament 0 20 40 60 80 100 PREPARED COMPOSITION (atom percent Pd) ρ 100 8. 7 Surface composition of binary alloys: (a) Pd-Au; (b) Pd-Ag.
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